The ManualFunctionKey can only be linked to manual functions. Add-ons don't have an Extension, so they cannot have manual functions. If you want to bring manual functions through the object definition, your object has to be a unit, not an add-on.
Of course, it is possible to create a manual function in the project that calls a command of an add-on. You cannot link the command to the manual function in CpStudio, but the call would have to be implemented manually in the PLC code.
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